Demons aren't always portrayed as evil entities in franchises and folklore, as some can be good at heart and fight for justice. These kinds of heroes may be good from start or originally evil, but due to the event in their lives, they ended up at the good side, whether it was occured from their backstory or confrontation with other heroes.
In spite of being good guys, heroic demons are still a dangerous opponent due to their demonic heritage, physiology, and powers. They could be chaotic due to these as well, which means they can be best ally/friend that other heroes could ever have, and the worst enemy that they could possibly imagine. Those who gained demonic powers (E.g. Jack-Jack Parr and Johnny Blaze) are fair game as well.
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