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Nanae Kayama is a old woman that is the twin sister of Yae, the mother of Orie and the grandmother of Licca Kayama. She was a habitant of Doll Kingdom, but after DeVaul menace, got away from there, and arrived in the Human World, where Licca (just a baby when she arrives there) lived a normal human life. She is a kind woman.
But, to protect her granddaughter, Nanae bring to the human world, 3 super-dolls, and a pendant to invoke they, to saves Licca. In the first episode, she gives to Licca a bracelet to notices danger to she, to she invokes Super Doll-Licca Chan after says special words. She even old and weary, struggles to invoke the doll, to save Licca.