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Primeape is a Fighting-type Pokémon from generation I. It evolves from Mankey at Level 28.
In the Anime
Ash spotted a Mankey and tried to catch it but failed, angering the Mankey in the process. In retribution, it stole his cherished hat, angering Ash. It evolved into primeape during a battle with team rocket.
Ash later thought of using Primeape in his gym battle against Erika, but due to its explosive temper and disobedience, he decided not to use it.