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Psyduck constantly suffers from a splitting headache that never heals. However, when its head aches really bad, its psychic powers are VERY powerful.
Misty has a Psyduck that she accidentally caught in Hypno's Naptime (She fell over and her Pokeball rolled out of her bag, and Psyduck let himself into the Pokeball, allowing himself to be caught.) It is a constant source of frustration for her, as it frequently emerges from its Poké Ball to attempt to battle the opponent in substitution of one of her other Pokémon. Despite this, she has been shown to deeply care for it. Despite being generally shown as dimwitted and oblivious, when its headache gets bad enough, it has been shown to use phenomenally powerful Psychic-typemoves which far exceed its normal ability.