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Psyduck is a duck-like Pokémon that appeared from Generation 1, and in the anime, it belongs to water Pokémon gym leader, Misty.

Psyduck constantly suffers from a splitting headache that never heals. However, when its head aches really bad, its psychic powers are VERY powerful.

Other Media

Super Smash Bros.

Psyduck first appears in Super Smash Bros. Melee in the Pokéfloat stage. In Super Smash Bros. Ultimate, Psyduck appears as an novice-ranked support spirit who increases the user's PSI. His spirit battle is against an green Squirtle on Saffron City and the screen occasionally flips.

Anime

Misty's Psyduck

Misty has a Psyduck that she accidentally caught in Hypno's Naptime (She fell over and her Pokeball rolled out of her bag, and Psyduck let himself into the Pokeball, allowing himself to be caught.) It is a constant source of frustration for her, as it frequently emerges from its Poké Ball to attempt to battle the opponent in substitution of one of her other Pokémon. Despite this, she has been shown to deeply care for it. Despite being generally shown as dimwitted and oblivious, when its headache gets bad enough, it has been shown to use phenomenally powerful Psychic-type moves which far exceed its normal ability.

Detective Pikachu (Movie)

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Game Characters
Red | Leaf | Blue Oak | Chase | Elaine | Trace | Ethan | Kris | Lyra | Silver | Brendan | May | Wally | Lucas | Dawn | Barry | Hilbert | Hilda | Cheren | Bianca | Nate | Rosa | Hugh | Calem | Serena | Shauna | Trevor | Tierno | Elio | Selene | Hau | Gladion | Victor | Gloria | Hop | Marnie | Bede | Klara | Avery | Keith | Rei | Akari

Professors
Professor Oak | Professor Elm | Professor Birch | Professor Rowan | Professor Juniper | Professor Sycamore | Professor Kukui | Professor Magnolia | Professor Sonia | Professor Willow | Professor Laventon

Pokédex Holders (Pokémon Adventures Characters)
Red | Blue Oak | Green | Yellow | Gold | Crystal | Silver | Ruby | Sapphire Birch | Emerald | Diamond | Pearl | Platinum Berlitz | Black | White | Blake | Whitley | X | Yvonne Gabena | Sun | Moon | Henry Sword | Casey Shield

Allies
Todd Snap | Looker | Riley | Cheryl | Georgia | N | Colress | Rood | Anthea and Concordia | Guzma | Wicke

Relatives
Daisy Oak | Johanna | Grace | Samson Oak | Lusamine | Mohn

Gym Leaders, Trial Captains, and Island Kahunas
Brock | Misty | Lt. Surge | Erika | Koga | Janine | Sabrina | Blaine | Blue Oak | Falkner | Bugsy | Whitney | Morty | Chuck | Jasmine | Pryce | Clair | Roxanne | Brawly | Wattson | Flannery | Norman | Winona | Tate and Liza | Wallace | Juan | Roark | Gardenia | Maylene | Crasher Wake | Fantina | Byron | Candice | Volkner | Cilan | Chili | Cress | Lenora | Burgh | Elesa | Clay | Skyla | Brycen | Drayden | Iris | Cheren | Roxie | Marlon | Shauntal Marshal | Grimsley | Caitlin | Alder | Viola | Grant | Korrina | Ramos | Clemont | Valerie | Olympia | Wulfric | Ilima | Hala | Lana | Kiawe | Mallow | Olivia | Sophocles | Acerola | Nanu | Mina | Hapu | Milo | Nessa | Kabu | Bea | Allister | Opal | Gordie | Melony | Piers | Marnie | Raihan

Elite Four, Finalists, and Quarter Finalists
Lorelei | Bruno | Agatha | Lance | Will | Koga | Karen | Sidney | Phoebe | Glacia | Drake | Aaron | Bertha | Flint | Lucian | Shauntal | Grimsley | Caitlin | Marshal | Malva | Siebold | Wikstrom | Drasna | Hala | Molayne | Olivia | Acerola | Kahili | Marnie | Hop | Nessa | Bea | Allister | Raihan

Champions
Blue Oak | Trace | Lance | Steven Stone | Wallace | Cynthia | Alder | Iris | Diantha | Elio | Selene | Leon

Battle Facility Leaders
Noland | Greta | Tucker | Lucy | Spenser | Brandon | Anabel | Palmer | Thorton | Dahlia | Darach | Argenta | Ingo | Emmet | Nita | Evelyn | Dana | Morgan | Red | Blue Oak

Main Pokémon
Pikachu | Bulbasaur | Charizard | Squirtle | Eevee | Butterfree | Sceptile | Buizel | Lucario | Snivy | Greninja | Incineroar | Psyduck | Vulpix | Scyther | Blaziken | Skitty | Piplup | Pachirisu | Sylveon | Chespin | Fennekin | Sparky | Riolu | Cinderace

Legendary/Mythical Pokémon
Mewtwo | Mew | Lugia | Ho-Oh | Entei | Celebi | Kyogre | Latias | Latios | Deoxys | Dialga | Palkia | Giratina | Cresselia | Darkrai | Shaymin | Arceus | Zekrom | Reshiram | Kyurem | Meloetta | Diancie | Zarude | Zacian and Zamazenta

Other Pokémon
Ivysaur | Venusaur | Blastoise | Raichu | Jigglypuff | Gyarados | Ditto | Snorlax | Pichu | Gardevoir | Metagross | Munchlax | Oshawott | Zoroark | Inkay | Malamar | Wyrdeer | Ursaluna | Basculegion | Sneasler | Hisuian Braviary | Enamorus

Poképark
Pikachu

Pokémon: Detective Pikachu
Detective Pikachu (Legendary Pictures) | Tim Goodman | Lucy Stevens

Pokémon Go
Professor Willow | Team Valor | Candela | Team Mystic | Blanche | Team Instinct | Spark | Pokémon Go Trainer

Groups and Organizations
Old Team Plasma | Team Yell | Galaxy Expedition Team | Diamond Clan | Pearl Clan | Pokédex Holders | Pokémon Trainers

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Playable Heroes
Alex | Banjo & Kazooie | Bayonetta | Bowser | Bowser Jr. | Byleth | Captain Falcon | Chrom | Cloud Strife | Corrin | Dark Pit | Diddy Kong | Donkey Kong | Dr. Mario | Duck Hunt | Eight | Erdrick | Falco Lombardi | Fox McCloud | Greninja | Ice Climbers | Ike | Incineroar | Inkling | Isabelle | Jigglypuff | Joker | Ken Masters | King Dedede | Kirby | Link | Little Mac | Lucario | Lucas | Lucina | Luigi | Luminary | Mario | Marth | Mega Man | Meta Knight | Mewtwo | Mii | Min Min | Mr. Game & Watch | Mythra | Ness | Olimar (Alph) (Pikmin) | Pac-Man | Palutena | Pichu | Pikachu | Pit | Pokémon Trainer (Red | Leaf) (Charizard | Ivysaur | Squirtle) | Princess Daisy | Princess Peach | Princess Zelda | Pyra | Richter Belmont | R.O.B. | Robin | Rosalina & Luma | Roy | Ryu | Samus Aran | Sheik | Shulk | Simon Belmont | Solid Snake | Solo | Sonic the Hedgehog | Sora | Steve | Terry Bogard | Toon Link | Villager | Wario | Wii Fit Trainer | Yoshi (Blue Yoshi | Light Blue Yoshi | Yellow Yoshi | Pink Yoshi | Purple Yoshi | Red Yoshi | Black Yoshi) | Young Link | Zero Suit Samus

Assist Trophies
Akira Yuki | Alucard | Ashley | Chef Kawasaki | Dillon | Elec Man | Gray Fox | Guile | Isaac | Isabelle | Jeff Andonuts | Jill | Kat and Ana | Knuckle Joe | Knuckles the Echidna | Krystal | Lakitu | Little Mac | Lyndis | Magnus | Midna | Phosphora | Prince of Sablé | Ray MK III | Riki | Rodin | Saki Amamiya | Samurai Goroh | Shadow the Hedgehog | Sheriff | Shovel Knight | Spring Man | Squid Sisters | Starfy | Sukapon | Takamaru | Tiki | Tingle | Waluigi | White Bomberman | Yuri Kozukata | Zero

Pokémon
Arceus | Alolan Raichu | Alolan Vulpix | Blastoise | Celebi | Chansey | Charizard | Chespin | Chikorita | Clefairy | Cyndaquil | Darkrai | Dedenne | Deoxys | Ditto | Eevee | Entei | Fennekin | Gardevoir | Genesect | Giratina | Groudon | Ho-Oh | Inkay | Keldeo | Kyogre | Kyurem | Latias and Latios | Lugia | Marill | Meloetta | Meowth | Metagross | Mew | Munchlax | Oshawott | Palkia | Piplup | Raikou | Scizor | Snivy | Snorlax | Suicune | Tapu Koko | Venusaur | Vulpix | Zoroark

Trophies/Spirits/Stickers
5-Volt | 9-Volt | 18-Volt | Absol | Adam Malkovich | Adelle | Aeron | Agitha | Aisya | Akuma | Alexandra Roivas | Alfonzo | Alfyn Greengrass | Allen | Alm | Amy Rose | Ana | Andy | Andy Bogard | Angela | Anjean | Ann Takamaki | Anna | Aerith Gainsborough | Aqua | Armor King II | Arthur | Aryll | Ashei | Ashley Robbins | Asuka Kazama | Athena Asamiya | Auto | Axel | Axl | Ayumi Tachibana | Azura | Baby Luigi | Baby Luma | Baby Mario | Baby Peach | Bandana Waddle Dee | Barbara | Barret Wallace | Barkle | Barst | Bass | Beat | Big Boss | Big the Cat | Blade Knight | Blanka | Blaze the Cat | Blaziken | Bord | Bomb Man | Boney | Bonkers | Bottles | Bow | Brittany | Brocque Mosieur | Broom Hatter | Bubbles | Bugzzy | Bulbasaur | Buneary | Buzz Buzz | Byrne | Byte and Barq | Caeda | Cait Sith | Calem | Calista | Camilla | Cammy White | Candy Kong | Cap'n Cuttlefish | Cappy | Captain (Another Code) | Captain (Mii Force) | Captain Rainbow | Captain Toad | Caroline and Justine | Catria | Celica | Centurions | Cetacea | Chao (Sonic) | Chao (Yuyuki) | Charlie | Charlie Nash | Charlotte | Charlotte Aulin | Charmander | Charmy Bee | Cheese | Chibi-Robo | Chris Redfield | ChuChu | Chun-Li | Chunky Kong | Ciela | Cid Highwind | Clark Still | Classic Sonic | Claude von Riegan | Claus | Cobalion | Cody Travers | Colin | Commander | Coo | Copper and Booker | Cord | Cordelia | Count Bleck | Cranky Kong | Cream the Rabbit | Cresselia | Crimson Loftwing | Culdra | Cuphead | Cupit | Cut Man | Cyrus Albright | Dan Hibiki| Daroach | Daruk | Darunia | Dash Bowman | Dee Jay | Deirdre | DeMille | Dhalsim | Dialga | Dieck | Diminutive Guardian | Dimitri | Dimitri Alexandre Blaiddyd | Din | Diskun | Dixie Kong | Doc Louis | Donbe | Donkey Kong Jr. | Dorothea Arnault | Doshin | Dr. Crygor | Dr. Light | Dr. Stewart | Dragonite | Drake Redcrest | Draug | Dreambert | Dribble and Spitz | Dunban | Duo | Duran | Duster | Dyna Blade | Dyntos | E. Honda | E-102 Gamma | E-123 Omega | Eagle | Eddie | Eddy | Edelgard von Hresvelg | Eirika | Eldstar | Elena | Elias | Elincia | Elise | Eliwood | Ellie the Elephant | Elline | Elma | Elvis | Emerl | Enguarde the Swordfish | Ephraim | Epona | Erik | Esna | Espio the Chameleon | Est | Eva | EVE | Expresso the Ostrich | Ezlo | F.L.U.D.D. | Fei Long | Felix | Fi | Fiora | Fire Man | Fishmen | Flint | Flygon | Flying Men | Four Giants | Frey | Freya | Fronks | Funky Kong | Futaba Sakura | Gabriel Belmont | Gaepora | Gaius | Gandrayda | Garchomp | Garet | Gen | General Pepper | Geno | Geo Stelar | Glaceon | Globox | Gloria | Goku | Golem | Gooey | Goombella | Goro Akechi | Goron | Great Fairy | Greil | Groose | Grutch | Guts Man | Guy | H'aanit | Hakkun | Hal "Otacon" Emmerich | Haohmaru | Happy Mask Salesman | Haru Okumura | Hawke | Hawkeye | Hector (Castlevania) | Hector (Fire Emblem) | Helix | Hendrik | Henry Fleming | Heracles | Heracross | Herman | Hikari | Hilda Valentine Goneril | Hinawa | Hinoka | Ho-Oh | Honey Queen | Hongo | Huey | Hugh Baldwin | Hydreigon | Hungry Luma | Hydreigon | Ibuki | Ice Man | Idea | Ifrit | Igor | Ilia | Impa | Ingrid Brandl Galatea | Inigo | Iori Yagami | Iris Archwell | Iron Golem | Isa Jo | Ivan | Jack-7 | Jade | Jagen | Jake | Jakob | James McCloud | Jeanne | Jenna Jessica | Jet the Hawk | Jill Valentine | Jimmy T. | Jin | Jin Kazama | Jinjo | Jody Summer | Joe Higashi | Jonathan Morris | Joshua | Julius Belmont | Juri Han | Juste Belmont | Kaepora Gaebora | Kafei | Kageshima Kurabe | Kairi | Karel | Karin Kanzuki | Kazuhira Miller | Kersti | Kevin | Kid Dracula | Kiddy Kong | Kim Kaphwan | Kine | King | King Zora | Kooper | Kumatora | Kunio | Kururin | Kyle Hyde | Kyo Kusanagi | L'Arachel | Landia | Landorus | Lanky Kong | Lappy | Leafeon | Leif | Leo | Leon Belmont | Leon S. Kennedy | Levias | Lilina | Lin Lee Koo | Linde | Linebeck | Ling Xiaoyu | Lip | Lissa | Lloyd | Loftwings | Loki | Lon'qu | Louie | Lubba | Luka Redgrave | Mach Rider | Madame Couture | Magolor | Makar | Makoto Niijima | Mallo | Mallow | Malon | Maria Renard | Marin | Marshall Law | Master Mummy | Mattel | Matthew | Max | Mechanica | Medli | Mega Man Volnutt | Mega Man X | MegaMan.EXE | Mei Ling | Melia Antiqua | Mermaid | Merric | Meryl Silverburgh | Mia | Micaiah | Milly | Minerva | Mini Mario | Mio & Mayu Amakura | Mipha | Misstar | Mist | Misty | Moe | Mokka | Mona | Moosh | Morag Ladir | Morgana | Muddy Mole | Mugman | Mumbo Jumbo | Musashi | Muskular | Myrrh | Nago | Nakoruru | Naomi Hunter | Nathan Graves | Navarre | Nayru | Nia | Nibbles | Nina Williams | Ninian | Ninjara | Nino | Ninten | Nyna | Octoling Girl & Octoling Boy | Off the Hook | Olaf | Olberic Eisenberg | Old Man Lobber | Olivia | Omega-Xis | Ooccoo | Ophilia Clement | Orbulon | Orville | Owain | Owl | Owlan | Palla | Paper Bowser | Paper Luigi | Paper Mario | Paper Princess Peach | Parasol Waddle Dee | Paul Phoenix | Paula Jones | Pauline | Paz Ortega Andrade | Penny Crygor | Peppy Hare | Perry | Piantas | Pitch | Plague Knight | Plasma Wisp | Plessie | Pneuma | Polterpup | Poo | Poochy | Poppi | Poppy Bros. Jr. | Primrose Azelhart | Prince Fluff | Prince Peasley | Prince Richard | Princess Shokora | Professor Chops | Professor Elvin Gladd | Professor Oak | Professor Sycamore | Protagonist (Astral Chain) | Protagonist (Glory of Heracles) | Protagonist (Magical Vacation) | Proto Man | ProtoMan.EXE | Rab | Rabbid Mario | Rabbid Peach | Rachel | Raiden | Ralf Jones | Rambi the Rhinoceros | Rattly the Rattlesnake | Raven | Ravio | Rayman | Raymond Bryce | Red XIII | Registeel | Reinhardt Schneider | Reshiram | Revali | Rex | Reyn | Rhea | Ribbon Girl | Rick | Ricky | Riesz | Riki | Riku | Ring Fit Trainee | Riolu | ROB 64 | Rock Pikmin | Rocky | Roll | Roll Caskett | Rosemary | Rouge the Bat | Rowlet | Roxas | Roy Campbell | Rush | Rusl | Russ | Rutger | Ruto | Ryo Sakazaki | Ryoma | Ryuji Sakamoto | Sagat | Sagi | Sakuna | Sakura | Sakura Kasugano | Sakura Samurai | Salsa | Sami | Saria | Satoru Amatsubo | Satoru Higashiyama | Seiuchi-kun | Seliph | Serena (Dragon Quest) | Serena (Pokémon) | Seteth | Seth | Severa | Shahra | Shanoa | Shantae | Sharla | Shaymin | Sheldon | Shield Knight | Shinobu | Shiva | Sigurd | Silver the Hedgehog | Sir Kibble | Sirius | Skarmory | Slippy Toad | Soma Cruz | Sophia | Soren | Sothe | Sothis | Spirit Who Loves Surprises | Sprixie Princesses | Squawks the Parrot | Squitter the Spider | Stanley | Starlow | Starly | Storm the Albatross | Strangelove | Stuffwell | Susie Haltmann | Swanky Kong | Sylvando | Sylveon | T. Hawk | Tac | Tails | Takumi | Tama | Tamagon | Tatsu | Tauros | Teddy | Tempo | Terra | Terrakion | Tethu | Tharja | The Boss | The King of Red Lions | The Mighty Jinjonator | The President | The Stork | The Wandering Samurai | Therion | Tifa Lockhart | Tikal the Echidna | Tiny Kong | Tippi | Titania | Toad | Toadette | Toadsworth | Tomatrio | Tooty | Tora | Totodile | Travis Touchdown | Treble | Tressa Colzione | Trevor Belmont | Tricky | Tron Bonne | Tsubasa Oribe | Twintelle | Tyranitar | Urbosa | Valoo | Vector the Crocodile | Ventus | Veronica | Villagers (Minecraft) | Vincent Valentine | Viridi | Virizion | Vivian | Waddle Dee | Waddle Doo | Wanda | Wave the Swallow | Welt Neugia | Wentworth | Wheelie | Winky the Frog | Wonder-Black | Wonder-Blue | Wonder-Green | Wonder-Pink | Wonder-Red | Wonder-White | Wonder-Yellow | Wrinkly Kong | Wrys | Xananab | Xander | Xion | Yang | Yoko Belnades | Yoshi Kid | Yoshimitsu | Young Cricket | Yuffie Kisaragi | Yun | Yusuke Kitagawa | Zael | Zangief | Zeke von Genbu | Zekrom | Zip | Zora |

Others
Altaïr Ibn-La'Ahad | Blue Mary | Chang Koehan | Chocobos | Choi Bounge | Dante | Doomslayer | Dragonborn | Gil | Goemon | Goro Daimon | Guardians of Light | Jacky Bryant | King (SNK) | Master Hand | Lloyd Irving | Rabbid | Rock Howard | Saïx | Sans | Tung Fu Rue | Yu Narukami | Yuri Sakazaki

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