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054Psyduck
Psyduck is a duck-like Pokémon that appeared from generation I, and in the anime, it belongs to water Pokémon gym leader, Misty.

Psyduck constantly suffers from a splitting headache that never heals. However, when its head aches really bad, its psychic powers are VERY powerful. 

Misty's Psyduck

Misty has a Psyduck that she accidentally caught in Hypno's Naptime (She fell over and her Pokeball rolled out of her bag, and Psyduck let himself into the Pokeball, allowing himself to be caught.) It is a constant source of frustration for her, as it frequently emerges from its Poké Ball to attempt to battle the opponent in substitution of one of her other Pokémon. Despite this, she has been shown to deeply care for it. Despite being generally shown as dimwitted and oblivious, when its headache gets bad enough, it has been shown to use phenomenally powerful Psychic-type moves which far exceed its normal ability. 

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Main Characters:
Ash Ketchum | Pikachu | Misty | Brock | Tracey Sketchit | May | Max | Dawn | Iris | Cilan | Serena | Clemont | Bonnie | Kiawe | Lillie | Mallow | Sophocles | Lana | Jimmy | | Koharu

Allies:
Professor Samuel Oak | Gary Oak | Officer Jenny | Nurse Joy | Todd Snap | Ritchie | Casey | Sakura | Drew | Steven Stone | Sanda | Zoey | Kenny | Barry | Looker | Riley | Lyra | Khoury | Professor Aurea Juniper | Trip | Bianca | Virgil | Georgia | N | Anthea and Concordia | Alexa | Professor Sycamore | Sawyer | Alain | Aria | Tierno | Shauna | Trevor | Clembot | Sanpei | Professor Kukui | Gladion

Relatives: Delia Ketchum | The Sensational Sisters | Flint | Norman | Caroline | Johanna | Chili | Cress | Grace | Meyer | Lusamine | Gladion

Gym Leaders: Brock | Misty | Erika | Jasmine | Clair | Norman | Maylene | Fantina | Falkner | Candice | Cilan | Iris | Viola | Grant | Korrina | Ramos | Clemont | Valerie | Olympia | Wulfric

Elite Four: Bruno | Lance

Champions: Cynthia | Diantha

Movie Characters: Meoldy | Maren | Diana | Towa | Bianca | Kidd Summers | Sir Aaron | Rafe | Jack Walker | Lizabeth | Alice | Maury

Pokemon: Mewtwo | Mew | Lugia | Ho-Oh | Entei | Celebi | Latias | Latios | Jirachi | Deoxys | Giratina | Darkrai | Azlef | Mesprit | Uxie | Shaymin | Arceus | Victini | Zekrom | Reshiram | Kyurem | Keldeo | Meloetta | Diancie | Zygarde | Pichu Brothers | Team Go-Getters | Team Poképals

Main Pokémon: Bulbasaur | Charizard | Squirtle | Butterfree | Totodile | Noctowl | Heracross | Sceptile | Infernape | Buizel | Snivy | Greninja | Goodra | Psyduck | Vulpix | Scyther | Blaziken | Beautifly | Skitty | Piplup | Buneary | Pachirisu | Ambipom | Axew | Excadrill | Dragonite | Pansage | Sylveon | Chespin | Bunnelby | Dedenne | Luxray | Turtonator | Togedemaru | Snowy | Sparky

Game Characters: Red | Ethan | Brendan | Nate | Rosa | Calem | Sun | Moon | Hau | Gloria | Keith | Kate | Summer | Murph

Teams
Team Plasma (Rood | Colress)
Team Flare (Malva)
Cipher (Ein | Eldes)

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